Methods and systems for liquid desiccant air conditioning system retrofit

ABSTRACT

Methods and systems are disclosed for utilizing liquid desiccant air conditioning systems in connection with existing HVAC equipment to achieve reductions in electricity consumption.

CROSS REFERENCE TO RELATED APPLICATIONS

This application is a division of U.S. patent application Ser. No. 14/212,263 filed on Mar. 14, 2014, entitled METHODS AND SYSTEMS FOR LIQUID DESICCANT AIR CONDITIONING SYSTEM RETROFIT, which claims priority from U.S. Provisional Patent Application No. 61/782,579 filed on Mar. 14, 2013, entitled METHODS AND SYSTEMS FOR LIQUID DESICCANT AIR CONDITIONING SYSTEM RETROFIT, both of which are hereby incorporated by reference.

BACKGROUND

The present application relates generally to the use of liquid desiccants to dehumidify and cool, or heat and humidify an air stream entering a space. More specifically, the application relates to an optimized system configuration to retrofit 2- or 3-way liquid desiccant mass and heat exchangers that employ micro-porous membranes to separate the liquid desiccant from an air stream in large commercial and industrial buildings while at the same time modifying existing Heating Ventilation and Air Conditioning (HVAC) equipment to achieve a significant reduction in electricity consumption in the building.

Desiccant dehumidification systems—both liquid and solid desiccants—have been used parallel to conventional vapor compression HVAC equipment to help reduce humidity in spaces, particularly in spaces that require large amounts of outdoor air or that have large humidity loads inside the building space itself. (ASHRAE 2012 Handbook of HVAC Systems and Equipment, Chapter 24, p. 24.10). Humid climates, such as for example Miami, Fla. require a lot of energy to properly treat (dehumidify and cool) the fresh air that is required for a space's occupant comfort. Conventional vapor compression systems have only a limited ability to dehumidify and tend to overcool the air, oftentimes requiring energy intensive reheat systems, which significantly increase the overall energy costs, because reheat adds an additional heat-load to the cooling coil. Desiccant dehumidification systems—both solid and liquid—have been used for many years and are generally quite efficient at removing moisture from the air stream. However, liquid desiccant systems generally use concentrated salt solutions such as ionic solutions of LiCl, LiBr or CaCl₂ and water. Such brines are strongly corrosive, even in small quantities, so numerous attempts have been made over the years to prevent desiccant carry-over to the air stream that is to be treated. In recent years, efforts have begun to eliminate the risk of desiccant carry-over by employing micro-porous membranes to contain the desiccant.

Liquid desiccant systems generally have two separate functions. The conditioning side of the system provides conditioning of air to the required conditions, which are typically set using thermostats or humidistats. The regeneration side of the system provides a reconditioning function of the liquid desiccant so that it can be re-used on the conditioning side. Liquid desiccant is typically pumped between the two sides. A control system is used to properly balance the liquid desiccant between the two sides as conditions necessitate and that excess heat and moisture are properly dealt with without leading to over-concentrating or under-concentrating the desiccant.

In large stores, supermarkets, commercial and industrial buildings, energy is wasted because the existing unitary HVAC units serving the building do not adequately dehumidify the ventilation air that they provide to the building. This excess humidity winds up being condensed out of the air with excess energy usage from refrigeration and freezer equipment inside the building, which creates a load on that equipment resulting in a higher than necessary energy consumption.

Older buildings typically have been designed with HVAC equipment that recirculates a large portion (80-90%) of the air from the space through its cooling coil. The equipment takes in approximately 10-20% of fresh outside air, which as discussed above requires dehumidification, which is not adequately done by this equipment. At time of construction and design, engineers will sometime add a desiccant system to create the necessary dehumidification, but such equipment is heavy, complex and expensive and is not retrofittable on buildings that were not originally designed to accommodate them.

There thus remains a need to provide a retrofittable cooling system for buildings with high humidity loads, wherein the dehumidification of outside air can be accommodated at low capital and energy costs.

BRIEF SUMMARY

Provided herein are methods and systems used for the efficient cooling and dehumidification of an air stream in a large commercial or industrial building using a liquid desiccant. In accordance with one or more embodiments, the liquid desiccant flows down the face of a support plate as a falling film. In accordance with one or more embodiments, the desiccant is contained by a microporous membrane, and the air stream is directed in a primarily vertical or primarily horizontal orientation over the surface of the membrane and whereby both latent and sensible heat are absorbed from the air stream into the liquid desiccant. In accordance with one or more embodiments, the support plate is filled with a heat transfer fluid that ideally flows in a direction counter to the air stream. In accordance with one or more embodiments, the system comprises a conditioner that removes latent and sensible heat through the liquid desiccant into the heat transfer fluid and a regenerator that rejects the latent and sensible heat from the heat transfer fluid to the environment. In accordance with one or more embodiments, the heat transfer fluid in the conditioner is cooled by a refrigerant compressor or an external source of cold heat transfer fluid. In accordance with one or more embodiments, the regenerator is heated by a refrigerant compressor or an external source of hot heat transfer fluid. In accordance with one or more embodiments, the refrigerant compressor is reversible to provide heated heat transfer fluid to the conditioner and cold heat transfer fluid to the regenerator, and the conditioned air is heated and humidified and the regenerated air is cooled and dehumidified.

In accordance with one or more embodiments, a liquid desiccant membrane system employs an indirect evaporator to generate a cold heat transfer fluid wherein the cold heat transfer fluid is used to cool a liquid desiccant conditioner. Furthermore, in one or more embodiments, the indirect evaporator receives a portion of the air stream that was earlier treated by the conditioner. In accordance with one or more embodiments, the air stream between the conditioner and indirect evaporator is adjustable through some convenient means, for example through a set of adjustable louvers or through a fan with adjustable fan speed. In one or more embodiments, the water supplied to the indirect evaporator is seawater. In one or more embodiments, the water is waste water. In one or more embodiments, the indirect evaporator uses a membrane to inhibit or prevent carry-over of non-desirable elements from the seawater or waste water. In one or more embodiments, the water in the indirect evaporator is not cycled back to the top of the indirect evaporator such as would happen in a cooling tower, but between 20% and 80% of the water is evaporated and the remainder is discarded.

In accordance with one or more embodiments, the indirect evaporator is used to provide heated, humidified air to a supply air stream to a space while a conditioner is simultaneously used to provide heated, humidified air to the same space. This allows the system to provide heated, humidified air to a space in winter conditions. The conditioner is heated and is desorbing water vapor from a desiccant and the indirect evaporator can be heated as well and is desorbing water vapor from liquid water. In combination the indirect evaporator and conditioner provide heated humidified air to the building space for winter heating conditions.

In accordance with one or more embodiments, some number of Liquid Desiccant Air Conditioning systems (LDACs) is installed at existing large stores, supermarkets or other commercial or industrial buildings to replace a subset of the existing unitary heating ventilating and air conditioning (HVAC) recirculating rooftop units (RTUs) already present. In accordance with one or more embodiments, the new liquid desiccant air conditioning units are operated to provide heated or cooled 100% outside air ventilation to the conditioned space. In accordance with one or more embodiments, the remaining RTUs are modified in such a way that they no longer supply outside air to the space, but become 100% recirculating RTU's. In one or more embodiments, the modification is achieved by removing power to a damper motor. In one or more embodiments, the modification is achieved by removing a lever from a damper mechanism. In accordance with one or more embodiments, the remaining RTUs are modified to have a higher evaporator temperature so that moisture no longer condenses on the evaporator coils and the unit becomes more energy efficient. In one or more embodiments, the increase in evaporator temperature is achieved by replacing an expansion valve. In one or more embodiments, the increase in evaporator temperature is achieved by adding an APR valve such as the valve assembly supplied by Rawal Devices, Inc. of Woburn, Mass. In one or more embodiments, the increase in evaporator temperature is achieved by adding a hot-gas bypass system or some other convenient means of increasing the evaporator temperature.

In accordance with one or more embodiments, the new liquid desiccant air conditioning units provide all of the cooled, dehumidified outside air ventilation required by the building during the cooling season and warm humidified outside air ventilation during the heating season. The remaining existing unitary HVAC units have their outside air dampers shut so that they only provide heating or cooling of the indoor air. The benefit of this system retrofit that the new LDACs are more energy efficient and effective at dehumidifying the required ventilation air than the unitary HVAC units they replace. Another benefit of this system approach is that by the improved ability to reduce the space humidity in the building, the energy used by refrigeration and freezer units inside of the conditioned space is significantly reduced because they waste less energy having to condense humidity out of the air. Furthermore, by modifying the remaining RTUs their energy consumption is also reduced. And lastly the advantage of replacing only a portion of the RTUs the cost of the upgrade is relatively minor since one can elect to replace mostly the oldest RTUs that are due for replacement anyway and payback periods are short because of the low upgrade cost and large energy savings.

In accordance with one or more embodiments, a liquid desiccant air conditioning system is constructed of repeatable membrane module elements and membrane module support tubs. In one or more embodiments, the scalable membrane modules are sized so as to fit through a standard access hatch for a roof with an opening of about 2.5 ft×2.5 ft. In one or more embodiments, the repeatable module support tubs are arranged in a linear fashion in such a way that the module support tubs form a support structure and an air duct simultaneously. In one or more embodiments, the module support tubs are hollow. In one or more embodiments, the module support tubs have double walls so that they can hold a liquid. In one or more embodiments, the liquid is a liquid desiccant. In one or more embodiments, the liquid desiccant is stratified with higher concentrations near the bottom and lower concentrations near the top of the tub. In one or more embodiments, the tub bottom is sloped so as the conduct any spilled liquid to a single corner of the tub. In one or more embodiments, the corner is equipped with a sensor or detector that can detect if any liquid has collected in the corner. In one or more embodiments, such a sensor is a conductivity sensor. In one or more embodiments, the module support tubs have openings on both ends. In one or more embodiments, the two ends are used to provide two different air streams into a series of support tubs. In one or more embodiments, the air streams are a return air stream and an outside air air-stream.

In accordance with one or more embodiments, a first series of membrane modules and module support tubs are arranged in a primarily linear fashion with a duct section that allows for a majority of air to be entered into a building and a portion of air to transported to a second series of membrane modules and module support tub sections. In one or more embodiments, the first series of modules and support tubs contain a membrane conditioner. In one or more embodiments, the membrane conditioner contains a desiccant behind the membrane. In one or more embodiments, the second series of modules contain a membrane conditioner. In one or more embodiments, the second conditioner contains water behind the membrane. In one or more embodiments, the water is seawater. In one or more embodiments, the water is waste water. In one or more embodiments, the water is potable water. In one or more embodiments, the air flow in the second series of membrane modules and module support tubs is reversible. In one or more embodiments, the first series of membrane modules receives a hot heat transfer fluid in winter mode from a heat source and receives a cold heat transfer fluid in summer mode. In one or more embodiments, the second series of membrane modules supplies the cold heat transfer fluid to the first series of membrane module in cooling mode and receives a hot heat transfer fluid from a heat source in winter mode. In one or more embodiments, the first series and second series of modules receive hot heat transfer fluid from the same heat source in winter mode.

In no way is the description of the applications intended to limit the disclosure to these applications. Many construction variations can be envisioned to combine the various elements mentioned above each with its own advantages and disadvantages. The present disclosure in no way is limited to a particular set or combination of such elements.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 illustrates an exemplary 3-way liquid desiccant air conditioning system using a chiller or external heating or cooling sources.

FIG. 2 shows an exemplary flexibly configurable membrane module that incorporates 3-way liquid desiccant plates.

FIG. 3 illustrates an exemplary single membrane plate in the liquid desiccant membrane module of FIG. 2.

FIG. 4 shows an exemplary building roof layout showing existing rooftop units (RTUs) and RTUs that would be replaced as part of a retrofit.

FIG. 5 shows a schematic aspect of an exemplary recirculating rooftop unit on a building space.

FIG. 6 shows a schematic aspect of an exemplary modified recirculating rooftop unit assisted by a liquid desiccant dedicated outdoor air system.

FIG. 7 depicts a psychrometric chart showing the processes of an exemplary recirculating rooftop unit as well as the liquid desiccant dedicated outdoor air system.

FIG. 8 shows an implementation of an exemplary scalable liquid desiccant dedicated outdoor air system.

FIG. 9A shows a schematic diagram of the conditioner side of the system of FIG. 8.

FIG. 9B shows a schematic diagram of the regenerator side of the system of FIG. 8.

FIG. 10 shows how the system of FIG. 8 can be expanded to increase the system's air flow and cooling capacity.

FIG. 11 shows an alternate embodiment of the system of FIG. 8 wherein the chiller has been replaced by an indirect evaporative cooling system.

FIG. 12 shows a detail of the membrane mass and heat exchanger tub support structure of FIG. 8.

DETAILED DESCRIPTION

FIG. 1 depicts a new type of liquid desiccant system as described in more detail in U.S. Patent Application Publication No. US 20120125020, which is incorporated by reference herein. A conditioner 101 comprises a set of plate structures that are internally hollow. A cold heat transfer fluid is generated in cold source 107 and entered into the plates. Liquid desiccant solution at 114 is brought onto the outer surface of the plates and runs down the outer surface of each of the plates. The liquid desiccant runs behind a thin membrane that is located between the air flow and the surface of the plates. Outside air 103 is now blown through the set of wavy plates. The liquid desiccant on the surface of the plates attracts the water vapor in the air flow and the cooling water inside the plates helps to inhibit the air temperature from rising. The treated air 104 is put into a building space.

The liquid desiccant is collected at the bottom of the wavy plates at 111 and is transported through a heat exchanger 113 to the top of the regenerator 102 to point 115 where the liquid desiccant is distributed across the wavy plates of the regenerator. Return air or optionally outside air 105 is blown across the regenerator plate and water vapor is transported from the liquid desiccant into the leaving air stream 106. An optional heat source 108 provides the driving force for the regeneration. The hot transfer fluid 110 from the heat source can be put inside the wavy plates of the regenerator similar to the cold heat transfer fluid on the conditioner. Again, the liquid desiccant is collected at the bottom of the wavy plates 102 without the need for either a collection pan or bath so that also on the regenerator the air flow can be horizontal or vertical. An optional heat pump 116 can be used to provide cooling and heating of the liquid desiccant. It is also possible to connect a heat pump between the cold source 107 and the hot source 108, which is thus pumping heat from the cooling fluids rather than the desiccant.

FIG. 2 describes a 3-way heat exchanger as described in further detail in U.S. patent application Ser. Nos. 13/915,199 filed on Jun. 11, 2013, 13/915,222 filed on Jun. 11, 2013, and 13/915,262 filed on Jun. 11, 2013, which are all incorporated by reference herein. A liquid desiccant enters the structure through ports 304 and is directed behind a series of membranes as described in FIG. 1. The liquid desiccant is collected and removed through ports 305. A cooling or heating fluid is provided through ports 306 and runs counter to the air stream 301 inside the hollow plate structures, again as described in FIG. 1 and in more detail in FIG. 3. The cooling or heating fluids exit through ports 307. The treated air 302 is directed to a space in a building or is exhausted as the case may be.

FIG. 3 describes a 3-way heat exchanger as described in more detail in U.S. Provisional Patent Applications Ser. No. 61/771,340 filed on Mar. 1, 2013, which is incorporated by reference herein. The air stream 251 flows counter to a cooling fluid stream 254. Membranes 252 contain a liquid desiccant 253 that is falling along the wall 255 that contain a heat transfer fluid 254. Water vapor 256 entrained in the air stream is able to transition the membrane 252 and is absorbed into the liquid desiccant 253. The heat of condensation of water 258 that is released during the absorption is conducted through the wall 255 into the heat transfer fluid 254. Sensible heat 257 from the air stream is also conducted through the membrane 252, liquid desiccant 253 and wall 255 into the heat transfer fluid 254.

FIG. 4 shows an example of a commercial or industrial building 403 rooftop. Some of the existing Roof Top Units (RTUs) 401 are kept in place and modified to provide only sensible cooling and are further modified to no longer accept outside air. A few (typically 1 in 3 to 1 in 5) of the unitary rooftop units 402 are to be replaced with new liquid desiccant air conditioning (LDAC) dedicated outdoor air units (DOAS). The replacement units 402 are chosen based on age of the equipment that they are replacing as well as based on the air distribution requirements to ensure that fresh air is distributed evenly in the space.

FIG. 5 shows a schematic diagram of a typical RTU 401 installed on a building 403. The RTU will have between 10 and 25% outside air 503 and provide about 300-400 Cubic Feet per Minute (CFM) of total air flow per ton of cooling capacity. A typical 10 ton RTU will thus provide about 3,000 to 4,000 CFM of total air 505 with 300 to 1,000 CFM of outside air mixed in. It is well known that the outside ventilation air can represent more than 60% of the humidity load in grocery stores. (ASHRAE 2012 Handbook of HVAC Systems and Equipment, Chapter 24, p. 24.10). The air 505 supplied to the space is nearly 100% saturated unless some form of reheating is employed. Reheating however adds a significant heat load to the cooling coil since a lot of air 501 that is returned to the RTU 401 is internally directed 504 to the cooling coil and a small portion 502 is exhausted, typically about the same amount as the RTU took in. The evaporator coil 506 is providing the primary cooling function of the mixed air stream 503 and 504. Compressor 507 is providing a refrigerant 508 and rejecting its heat to condenser 509. A typical condenser will have some 800 CFM of outside air 510 per ton of cooling, or about 8,000 CFM for a 10-ton unit. An expansion valve 511 provides the cold liquid refrigerant to the evaporator coil 506.

FIG. 6 shows how the RTU 401 of FIGS. 4 and 500 can be modified and supplemented by a liquid desiccant dedicated outdoor air system 402. The RTU 401 has been modified to no longer provide or take in outside air. As a result, only return air 501 from the building is recirculated 601 through the evaporator coil 506. Alternatively, the RTU is modified to reduce the intake of outside air. The evaporator temperature has also been increased from a normal 40 F to about 50-60 F. There are several ways that this can be accomplished: one can replace the expansion valve 511 with a different valve 610 set for a higher evaporator temperature. Other ways to increase the evaporator temperature is for example to provide an APR bypass valve made by Rawal Devices, Inc., Woburn, Mass. 01888-0058. By increasing evaporator temperature, the cooling load of the remaining RTU is reduced and the system operates more efficiently.

One of the RTUs is replaced with a liquid desiccant system 402 as discussed earlier. The main liquid desiccant system components are the conditioner 603—which can be like component 101 in FIG. 1 and the regenerator 606—which can be like component 102 in FIG. 1. An optional compressor 609 pumps heat from the conditioner to the regenerator using refrigerant 608 and using expansion valve 610. Outside air 605 is brought through the conditioner 606 and supplied 607 at a lower temperature and humidity than the space requires. Return air 602 enters the regenerator 606 where it picks up heat and moisture after which is exhausted 604. (In case return air is unavailable for the liquid desiccant system 402, the air stream 602 can comprise outside air.) The liquid desiccant system is sized in such a way that it provides all of the outside air as was previously provided by the recirculating RTU's 401. Since the LDAC is providing dry, cool air, the space itself is much drier which will reduce the load on refrigeration equipment and freezers in the space.

FIG. 7 shows a psychrometric chart of the processes involved in the recirculating RTU and the liquid desiccant system. A conventional RTU takes in 10-25% of outside air (“OA”) and mixes that air with return air from the building (“RA”). The resulting mixed air (“MA”) point is determined by the amount of outside and return air that is combined. The cooling coil 506 subsequently takes the mixed air (“MA”) and cools it to the saturation line where water vapor condenses out and ultimately supplies air to the space at low temperature but near saturation level (“COIL”). This air needs to be heated by the building somehow, which on hot sunny days can be naturally done, but on cloudy days or mid temperature days may not occur unless an additional reheat system is employed. In supermarkets, grocery stores and the like, the refrigeration cases and freezers can provide an additional cooling effect, indicated by the arrow (“FR”) from the return air position (“RA”). As can be seen in the figure, the additional sensible cooling provided by the freezers and refrigerators and a lack of reheat, result in a space that is too cold and too humid, with relative humidity exceeding 70%. Furthermore, water sprayers in vegetable sections and short cycling of the RTU's make this situation even worse.

The liquid desiccant air conditioning system of FIG. 6 however, also takes in outside air (“OA”) and produces cooler, dry air (“DA”) to the space. The additional cooling by the remaining RTUs and freezers and refrigerators (“RTU”) results in a much smaller increase in relative humidity which can be avoided by simply not operating the RTU's unless necessary.

FIG. 8 illustrates an embodiment of a liquid desiccant air conditioning system (LDAC) 402 that is able to provide cool, dry air to a space from 100% outside air. Several of the components in the system of FIG. 8 have been identified in FIG. 6. The conditioner modules 603 (of which there are 4 in this example), contain the membrane plate structures as were shown in FIGS. 1-3. Similarly, the regenerator modules 606 (of which there are also 4 in this example) have similar construction to the conditioner modules. Outside air 605 is entering the conditioner section through louvers 802. The outside air is then transported through optional internal ducts 806, downward through the conditioner modules 603 and then through the tub modules 803 to exit the system as supply air 607. The return air from the building (not shown) receives some additional outside air 805 through louvers 807. This air is then transported through regenerator modules 606 and regenerator duct modules 812 and eventually exhausted out of the system (not shown). A power interface module 801 and an integral chiller/heat pump system 609 provide electrical facilities and hot and cold water for the regenerator and conditioner modules respectively. As shown in the figure, the system has 4 conditioner and 4 regenerator modules, mounted 2 at a time on tub supports 803. The size of the modules was chosen such that they are able to fit through standard roof access hatches. As can be seen from the figure, it would be very easy to add additional tub modules 803 and membrane conditioner or regenerator modules 603 and 606. The right side of the system of FIG. 808 is terminated by removable end plate 800 for the conditioner tub modules, removable end plate 810 for the conditioner duct 806, and removable end plate 809 for the regenerator duct. Cold water supply and cold water return and hot water supply and hot water return are shown as item 811 in the figure. The louver 807 is mounted to the last tub module and is easily removed and mounted on a different tub module. Also shown is one of the desiccant pumps 813 which will be discussed in more detail under FIG. 900 and FIG. 12. The whole system is mounted on a modular support frame 804.

FIG. 9A illustrates the conditioner side of the system of FIG. 8. As mentioned before, outside air 605 enters the system through louvers 802. Fan 901 brings the air through ducts 806. Conditioner membrane modules 603 cool and dehumidify the air stream which is transported through tubs 803 into the supply air stream 607. End plates 808 and 810 terminate the system. Water lines for cold water supply and return 811 bring cold water to the individual conditioner modules 603. For clarity only one of the water lines 904 is shown, the other modules 603 receive cooling water in a similar fashion. The desiccant pump 813 receives liquid desiccant from the tub modules 803. The pump distributes the liquid desiccant to the conditioner modules 603 through supply lines 905. For clarity the desiccant supply lines for two of the conditioner modules are shown in the figure and the remainder has been omitted. As can be seen in the figure, the desiccant drains out of the conditioner modules back into the tub modules 803.

FIG. 9B shows—similarly to FIG. 9A—the main components of the regenerator side of the system of FIG. 8. Return air 602 from the building is directed through the tub modules 803 and through the regenerator modules 606. The regenerator ducts 812 conduct the air streams back through fan 902 and louver 903 where the hot, humid air 604 is exhausted. Since in buildings the amount of available return air can be less than the amount of air that is supplied to the building (supply air 607 is larger than return air 602) and additional outside air stream 805 can be mixed in through louver 807. This helps to ensure that the system has adequate air supply for the regenerator modules. Similar to the conditioner side, desiccant pump 908 provides liquid desiccant to the regenerator modules 606 through supply lines 907. Hot water 906 is also supplied to the regenerator modules. For clarity only some of the water and desiccant lines have been shown.

It is also possible to reverse the direction of the chiller 609 in a winter operating mode so that the conditioner 603 receives hot heat transfer fluid and the regenerator 606 receives cold heat transfer fluid. In this mode the conditioner will desorb water vapor and humidify and heat the supply air stream 607 and the regenerator will absorb heat and water vapor from the return air stream 602 from the space. In effect the system will recover heat and moisture from the return air stream 602 in this mode.

FIG. 10 show the system of FIG. 8 with an additional section 1001 comprising 4 conditioner and 4 regenerator modules have been inserted in the system of FIG. 8. The chiller 1002 as well as the fans and water pumps (not shown) now need to be sized to accommodate for the increase in air flow and cooling load of the system. It will be apparent that one can continue to increase the air flow and cooling capacity of the system by continuing to add membrane models and other components, at least until the air flow capacity of the ducts and tubs is exceeded.

FIG. 11 shows a schematic diagram of an alternate embodiment of the linkable system of FIG. 6. The chiller section 609 from FIG. 6 and FIG. 8 has now been omitted in favor of an indirect evaporative cooling section 1111. The supply air 607 is partially diverted (typically between 0 and 30%) as air stream 1105 into duct 1101 and louver 1102 to enter tub 1103. The air stream now moves upward through membrane modules 1106. But unlike the conditioner modules and regenerator modules, these evaporator membrane modules have water rather than desiccant behind their membranes. Since the air stream 1105 is very dry, a large cooling effect can be obtained in the membrane modules 1106 by evaporating the water behind the membranes. This in turn results in the heat transfer fluid 1109 becoming substantially cooled. This cold heat transfer fluid 1109 can then be used to remove heat from the original membrane modules 603. The warmer heat transfer fluid 1110 is circulating back to the indirect evaporative cooling section 1111 from the conditioner modules 603. Since the evaporator modules 1106 evaporate water, there needs to be a constant supply of water 1113. This water can be clean drinking water, in which case the membranes on the evaporator modules 1106 are not absolutely necessary. In that case also, the remaining water can be drained 1115 from the membrane modules 1106 into the tub 1103 and removed from the tub by pump 1112 to be re-used at the top of the evaporative modules 1106. Attention has to be paid to ensure that like a conventional cooling tower, there is no buildup of scale and other contaminants. There are several methods common in the industry that can be employed to deal with scale issues, for example blow-down systems or ultrasonic precipitation.

However, the use of membrane in evaporator modules 1106 also enables the use of seawater or waste water: the membranes will contain any salt particles or other contamination. In this case, the intent is to evaporate only a portion (typically around 50% or less) of the water supplied by supply 1113. The concentrated remaining water is then drained through line 1114 and disposed of in an appropriate drainage system. The pump 1112 can now be omitted and no scaling or blow-down system is required. However, membrane fouling may become an issue and can be dealt with using flushing and a proper pre-filtration system. The exhaust air stream 1108 leaving the evaporator modules 1106 is warm and near saturation and is pulled through the system by fan 1107. It should be clear from the figure that when one adds additional conditioner modules 603 there should also be additional evaporator modules 1106. This can be easily accomplished by removing cover 1104 and adding an additional section 1111. Fan 1107 would also have to be sized larger and moved to the added section.

It is also possible to reverse the air stream 1105 while at the same time providing hot heat transfer fluid to the conditioner blocks 603. In this winter heating mode, the conditioner will desorb water vapor into the air stream 1105 and the conditioners 603 will combine to supply warm, moist air to the space 607.

FIG. 12 illustrates a detail cross section of the membrane module support tub 803 and part of the desiccant distribution system connected to it. The tub 803 is constructed as a hollow shell structure with walls 1205 and 1206. The inner area 1201 functions as a liquid desiccant storage tank. This is beneficial since it eliminates the need for a separate tank and since the volume is located directly below the membrane modules, syphoning of desiccant into the tank structure is enhanced. Furthermore, the tank structure allows for stratification of the desiccant wherein the higher concentration of desiccant can be found near the bottom of the tub and the lower concentration can be found near the top. The inner bottom 1202 of the tub 803 is slowed in such a way that any leaks from the membrane modules above will drain into a single corner where a detector or sensor can be located to indicate that a leak has occurred. Furthermore, bottom has a lip 1208 constructed in such a way that the air stream cannot transport any droplets that may fall from the membrane modules. The membrane modules physically sit on the support plate 1203 which has designed in rail features 1209 to allow for a tight air seal between the membrane modules and the tub structure. Since the tub 803 contains the desiccant for the system, pump 908 pulls desiccant from the lower port on the tub, pumps it to the top of the membrane module 603 wherefrom it drains by gravity back through drain 1204 into the top port of the tub. A secondary port 1207 allows for dilute desiccant to be removed and pumped to the regenerator modules which are set up in a similar fashion except that the regenerator pumps from the top port to the top of membrane modules 606 and removes concentrated desiccant from the bottom port back to the conditioner. The air duct 1210 can also be seen in the figure.

Having thus described several illustrative embodiments, it is to be appreciated that various alterations, modifications, and improvements will readily occur to those skilled in the art. Such alterations, modifications, and improvements are intended to form a part of this disclosure, and are intended to be within the spirit and scope of this disclosure. While some examples presented herein involve specific combinations of functions or structural elements, it should be understood that those functions and elements may be combined in other ways according to the present disclosure to accomplish the same or different objectives. In particular, acts, elements, and features discussed in connection with one embodiment are not intended to be excluded from similar or other roles in other embodiments. Additionally, elements and components described herein may be further divided into additional components or joined together to form fewer components for performing the same functions. Accordingly, the foregoing description and attached drawings are by way of example only, and are not intended to be limiting. 

1. A liquid desiccant air conditioning unit for treating an air stream entering a building space, comprising: a conditioner including a plurality of structures arranged in a substantially vertical orientation, each structure having at least one surface across which a liquid desiccant can flow, wherein the air stream flows between the structures such that the liquid desiccant dehumidifies the air stream in a warm weather operation mode and humidifies the air stream in a cold weather operation mode, each structure further includes a desiccant collector at a lower end of the at least one surface for collecting liquid desiccant that has flowed across the at least one surface of the structure; a tub module coupled to the conditioner comprising interior and exterior walls forming a hollow shell structure, wherein the air stream treated by the conditioner flows through an interior space in the tub module defined by the interior walls, and wherein liquid desiccant used in the conditioner flows through a space between the interior and exterior walls of the tub module; an apparatus for moving the air stream through the conditioner and tub module and into the building; and an apparatus for circulating the liquid desiccant through the conditioner.
 2. The liquid desiccant air-conditioning unit of claim 1, wherein the liquid desiccant air-conditioning unit is modular and can be coupled to one or more additional liquid desiccant air-conditioning units to increase air conditioning capacity, wherein a first duct is coupled to each of the liquid desiccant air-conditioning units to distribute the air stream among the liquid desiccant air-conditioning units, and wherein the tub modules of the liquid desiccant air-conditioning units are connected in series to collect and transfer air treated by the liquid desiccant air-conditioning units to the building.
 3. The liquid desiccant air-conditioning unit of claim 1, wherein the apparatus for moving the air stream comprises a fan or a blower.
 4. The liquid desiccant air-conditioning unit of claim 1, wherein the apparatus for circulating the liquid desiccant comprises a pump.
 5. The liquid desiccant air-conditioning unit of claim 1, wherein each of the plurality of structures in the conditioner includes a passage through which a heat transfer fluid can flow.
 6. The liquid desiccant air-conditioning unit of claim 1, wherein each of the plurality of structures in the conditioner includes a sheet of material positioned proximate to the outer surface of each structure between the liquid desiccant and an air stream, said sheet of material permitting transfer of water vapor between the liquid desiccant and an air stream.
 7. The liquid desiccant air-conditioning unit of claim 6, wherein the sheet of material comprises a membrane.
 8. The liquid desiccant air-conditioning unit of claim 1, wherein the conditioner is mounted on top of the tub module.
 9. A regenerator unit in a liquid desiccant air conditioning system, comprising: a regenerator including a plurality of structures arranged in a substantially vertical orientation, each structure having at least one surface across which a liquid desiccant can flow, wherein an air stream flows between the structures such that the liquid desiccant humidifies the air stream in a warm weather operation mode and dehumidifies the air stream in a cold weather operation mode, each structure further includes a desiccant collector at a lower end of the at least one surface for collecting liquid desiccant that has flowed across the at least one surface of the structure; a tub module coupled to the regenerator comprising interior and exterior walls forming a hollow shell structure, wherein the air stream to be treated by the regenerator flows into the regenerator through an interior space in the tub module defined by the interior walls, and wherein liquid desiccant used in the regenerator flows through a space between the interior and exterior walls of the tub module; an apparatus for moving the air stream through the regenerator and tub module; and an apparatus for circulating the liquid desiccant through the regenerator.
 10. The regenerator unit of claim 9, wherein the regenerator unit is modular can be coupled to one or more additional regenerator units to increase air conditioning capacity, wherein a first duct is coupled to each of the regenerator units to collect and transfer air out air treated by the regenerator units, and wherein the tub modules of the regenerator units are connected in series to distribute air to be treated by the regenerator units.
 11. The regenerator unit of claim 9, wherein the apparatus for moving the air stream comprises a fan or a blower.
 12. The regenerator unit of claim 9, wherein the apparatus for circulating the liquid desiccant comprises a pump.
 13. The regenerator unit of claim 9, wherein each of the plurality of structures in the regenerator includes a passage through which a heat transfer fluid can flow.
 14. The regenerator unit of claim 9, wherein each of the plurality of structures in the regenerator includes a sheet of material positioned proximate to the outer surface of each structure between the liquid desiccant and an air stream, said sheet of material permitting transfer of water vapor between the liquid desiccant and an air stream.
 15. The regenerator unit of claim 14, wherein the sheet of material comprises a membrane.
 16. The regenerator unit of claim 9, wherein the regenerator is mounted on top of the tub module.
 17. A desiccant air conditioning system for treating an air stream entering a building space, comprising: a conditioner including a plurality of first structures arranged in a substantially vertical orientation, each structure having at least one surface across which a liquid desiccant can flow, each structure also including a passage through which heat transfer fluid can flow, wherein the air stream flows between the structures such that the liquid desiccant dehumidifies and cools the air stream, and the heat transfer fluid cools the liquid desiccant; a regenerator connected to the conditioner for receiving liquid desiccant from the conditioner and causing the liquid desiccant to desorb water; an indirect evaporative cooling unit coupled to the conditioner for receiving the heat transfer fluid that has flowed through the first structures and a portion of the air stream that has been dehumidified and cooled by the conditioner, said indirect evaporative cooling unit including a plurality of second structures arranged in a substantially vertical orientation, each structure having at least one surface across which water is flowed, each structure also including a passage through which the heat transfer fluid from the conditioner is flowed, wherein the portion of the air stream received from the conditioner flows between the structures such that the water is evaporated into the air stream, resulting in cooling of the heat transfer fluid, and wherein the cooled heat transfer fluid is returned to the conditioner; an apparatus for moving the air stream through the conditioner and indirect evaporative cooling unit; an apparatus for circulating the liquid desiccant through the conditioner and regenerator; and an apparatus for circulating heat transfer fluid through the conditioner and the indirect evaporative cooling unit.
 18. The system of claim 17, wherein up to 30% of the air stream treated by the conditioner is diverted to the indirect evaporative cooling unit.
 19. The system of claim 17, wherein each of the plurality of second structures in the indirect evaporative cooling unit includes a sheet of material positioned proximate to the outer surface of each structure between the water and the air stream, said sheet of material permitting transfer of water vapor to the air stream.
 20. The system of claim 17, wherein the sheet of material comprises a membrane.
 21. The system of claim 17, wherein the water comprises seawater, wastewater, or drinking water.
 22. The system of claim 17, wherein the water comprises seawater, wastewater, or drinking water.
 23. The system of claim 17, wherein each of the plurality of first structures in the conditioner includes a sheet of material positioned proximate to the outer surface of each structure between the liquid desiccant and the air stream, said sheet of material permitting transfer of water vapor between the liquid desiccant and the air stream.
 24. The system of claim 23, wherein the sheet of material comprises a membrane. 